Take my response with a grain of salt as this isn't my expertise, but I would wonder if the compressor is starting to go or if you have a partial blockage in the system.
I recently filled mine up and the compressor made a horrendous noise and the cool air didn't last more than a couple days. Tried filling it again and it didn't do anything.
So, I'm about to replace the compressor, dryer, and orifice tube on my car. While I have it all apart I figured I'd do things right and flush the system out and then evacuate it before refilling it.
I should prolly take pics and create a write-up if I can remember to do so...
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Kinda sorta, yeah, no?
'02 Black GTP - RIP 03/03/08 ||| '06 Black G35 MT6 - Stock ||| '73 Chevy half ton(resurrected)